River transport of carbon to the ocean is not on a scale that will solve
our carbon dioxide problem, but we haven't known how much carbon the
world's rivers routinely flush into the ocean, until now. Scientists
calculated the first direct estimate of how much and in what form
organic carbon is exported by rivers. The estimate will help modelers
predict how this export may shift as Earth's climate changes.

While river transport of carbon to the ocean is not on a scale that will bail humans out of our CO2
problem, we don't actually know how much carbon the world's rivers
routinely flush into the ocean -- an important piece of the global
carbon cycle.
But in a study published May 14 in the journal Nature,
scientists from Woods Hole Oceanographic Institution (WHOI) calculated
the first direct estimate of how much and in what form organic carbon is
exported to the ocean by rivers. The estimate will help modelers
predict how the carbon export from global rivers may shift as Earth's
climate changes.
"The world's rivers act as Earth's circulatory system, flushing
carbon from land to the ocean and helping reduce the amount that returns
to the atmosphere in the form of heat-trapping carbon dioxide," said
lead author and geochemist Valier Galy. "Some of that carbon--'new'
carbon--is from decomposed plant and soil material that is washed into
the river and then out to sea. But some of it comes from carbon that has
long been stored in the environment in the form of rocks-- 'old'
carbon--that have been eroded by weather and the force of the river."
The scientists, who included Bernhard Peucker-Ehrenbrink, and Timothy
Eglinton (now at ETH Zürich), amassed data on sediments flowing out of
43 river systems all over the world, which cumulatively account for 20
percent of the total sediments discharged by rivers. The representative
rivers also encompassed a broad range of climates, vegetation,
geological conditions, and levels of disturbance by people.
From these river sediment flow measurements, the research team
calculated amounts of particles of carbon-containing plant and rock
debris that each river exported. They estimated that the world's rivers
annually transport 200 megatons (200 million tons) of carbon to the
ocean. The total equals about .02 percent of the total mass of carbon in
the atmosphere. That may not seem like a lot, but over 1000 to 10,000
years, it continues to add up to significant amounts of carbon (20 and
200 percent) extracted from the atmosphere.
Generally, plants convert CO2 from the atmosphere into
organic carbon via photosynthesis. But most of this carbon eventually
returns to the atmosphere when plant material (or animals that eat
plants) decompose. A small fraction of this material, however, ends up
in rivers. They carry it out to sea, where some settles to the seafloor
and is buried and disconnected from the atmosphere for millions of years
and eventually makes its way back to the surface in the form of rocks.
At the same time, rivers also erode carbon-containing rocks into
particles carried downstream. The process exposes carbon to air,
oxidizing the previously locked-up carbon into carbon dioxide that can
leak back out to the atmosphere. Until now, scientists had no way to
distinguish how much of the carbon whisked away by rivers comes from
either the biospheric or petrogenic (rock) sources. Without this
information, scientists' ability to model or quantitatively predict
carbon sequestration under different scenarios was limited.
To solve this dilemma, the scientists found a novel way to
distinguish for the first time the sources of that carbon--either from
eroded rocks or from decomposed plant and soil material. They analyzed
the amounts of carbon-14, a radioactive isotope, in the river particles.
Carbon-14 decays away within about 60,000 years, so it is present only
in material that came from living things, and not rocks. Subtracting the
portion of particles that did not contain carbon-14, the scientists
calculated the percentage that was derived from the terrestrial
biosphere: about 80 percent.
But even though biospheric carbon is the major source of carbon
exported by rivers, the scientists also discovered that rivers
surrounded by greater amounts of vegetation didn't necessarily transport
more carbon to the ocean. Instead, the export was "primarily controlled
by the capacity of rivers to mobilize and transport" particles. Erosion
is the key factor--the more erosion occurs along the river, the more
carbon it transfers to sea and sequesters from the air.
"The atmosphere is a small reservoir of carbon compared to rocks,
soils, the biosphere, and the ocean," the scientists wrote in Nature.
"As such, its size is sensitive to small imbalances in the exchange with
and between these larger reservoirs."
The new study gives scientists a firmer handle on measuring the
important, and heretofore elusive, role of global rivers in the
planetary carbon cycle and enhances their ability to predict how
riverine carbon export may shift as Earth's climate changes.
"This study will provide geochemical modelers with new insights on an
important link between the global carbon and water cycles," says Don
Rice, program director in the National Science Foundation's Division of
Ocean Sciences, a major funder of the research.
This is taken from Science Daily